catena-Poly[[(8-aminoquinoline-κ2N,N′)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N-[(8-aminoquinoline-κ2N,N′)cadmium]-di-μ-chlorido]
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چکیده
منابع مشابه
catena-Poly[(dichloridocadmium)-di-μ-chlorido-[bis(morpholinium-κO)cadmium]-di-μ-chlorido]
In the title compound, [Cd(2)Cl(6)(C(4)H(10)NO)(2)](n), the coordination geometry of each Cd(II) ion is distorted octa-hedral, but with quite different coordination environments. One Cd(II) atom is coordinated by four Cl atoms and two O atoms from two morpholinium ligands, while the other is coordinated by six Cl atoms. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride br...
متن کاملcatena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ4 N:N]]
The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations ...
متن کاملcatena-Poly[[trimethyl(4-sulfanylphenyl)azanium] [(chloridocadmate)-di-μ-chlorido]]
The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n) (n) (-) polyanion and a trimeth-yl(4-sulfanylphen-yl)aza-nium cation. The Cd(II) atom is penta-coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal-bipyramidal geometry. The trigonal-bipyramidal units are linked by two opposite shared faces, giving rise to infinite [CdCl(3)](n) chains parallel...
متن کاملcatena-Poly[bis(1,3-benzothiazol-3-ium) [[dichloridoantimonate(III)]-di-μ-chlorido-μ-oxido-[chloridoantimonate(III)]-μ-chlorido]]
The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two ...
متن کاملcatena-Poly[[chloridomercury(II)]-μ-1,4-diazabicyclo[2.2.2]octane-κ2 N:N′-[chloridomercury(II)]-di-μ-chlorido]
In the title coordination polymer, [Hg(2)Cl(4)(C(6)H(12)N(2))](n), each Hg(II) center within the chain is four-coordinated by one terminal Cl atom, two bridging μ(2)-Cl atoms, and one N-atom donor from a μ(2)-1,4-diaza-bicyclo-[2.2.2]octane (μ(2)-daco) ligand in a distorted tetra-hedral geometry. The daco ligand acts as an end-to-end bridging ligand and bridges adjacent Hg(II) centers, forming ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811051373